You cannot change the printer default settings for individual users. Settings made in the [Printer Properties] dialog box are applied to all users.
On the [Start] menu, point to [Settings], and then click [Printers].
The [Printers] window appears.
Click the icon of the printer you want to use.
On the [File] menu, click [Printing Preferences...].
The [Printing Preferences] dialog box appears.
Make the settings you require, and then click [OK].
The settings you make here are used as the default settings for all applications.
For details, see the printer driver Help.